A METHOD FOR PREPARING ORGANICALLY FUNCTIONALIZED MONODISPERSE NANOPARTICLES OF CATALYTICALLY ACTIVE AND NON-CATALYTICALLY ACTIVE NOBLE METALS
UCLA Technology Available For Licensing

Nanometer-scale crystallites of various metals and non-metals have received a great deal of attention in the past decade. For such crystallites, the electronic, thermodynamic, and chemical properties depend sensitively on size, shape, and surface composition. A major challenge to this field is the complete control over particle size, morphology, and surface composition. The preparation and isolation of truly monodisperse sized crystallites with well-characterized surfaces and of uniform shape is paramount to their success as applied materials.

Current methods of preparing catalytically active and non-catalytically active metals do not provide a means of consistently controlling the size, size distribution, and surface composition of these particles. UCLA researchers have recently developed a method of preparing monodisperse sized particles of uniform shape with well-defined surface compositions. Catalytically active metals such as platinum, palladium, and silver and non-catalytically active metals such as gold have been prepared.

In catalytic processes, the size and morphology of the particle is often of great concern as it determines catalytic reactivity and selectivity. Organically-functionalized nanometer-scale particles of catalytically-active metals have extremely high surface areas (a large number of catalytically active sites per particle) and unique size-dependent chemical behavior. This enables their application in a variety of homogenous and heterogeneous catalytic processes from petroleum cracking to polymer synthesis. The Pt, Pd, and Ag particles prepared by the UCLA researchers would be applicable here.

In reprographic processes, uniform particle size distributions lead to uniform film quality, and small particle sizes lead to enhanced film resolution. Specifically, it is small silver particles that form the amplification center in these conventional photographic processes. The Ag particles prepared by the UCLA researchers would be applicable here. Gold colloids are often employed as size-markers for measuring the dimensions of biological structures.

Reference: UCLA Case No. 1995-560 US Patent Number: 6,103,868

For additional technical details and current licensing
availability, please contact the following UCLA office:

UCLA Office of Intellectual Property
11000 Kinross Avenue, Suite #200
Los Angeles, CA 90095-7231
Tel: 310-794-0558 Fax: 310-794-0638
email: ncd@research.ucla.edu
Lead Inventor: Daniel Leff

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http://www.research.ucla.edu/tech

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